Microstructures and photocatalytic properties of Ag + and La 3+ surface codoped TiO 2 films prepared by sol–gel method

Abstract

Ag + and La 3+ surface codoped TiO 2 films were successfully prepared by the improved sol–gel and doping processes. The as-prepared specimens were characterized using differential thermal analysis-thermogravimetry (DTA–TG), X-ray diffraction (XRD), high-resolution field emission scanning electron microscopy (FE-SEM), X-ray energy dispersive spectroscopy (EDS), Brunauer–Emmett–Teller (BET) surface area, Photoluminescence spectrum (PL) and UV–vis diffuse reflectance spectroscopy. The photocatalytic activities of the films were evaluated by degradation of an organic dye in aqueous solution. The results of XRD, FE-SEM and BET analyses indicated that the TiO 2 films were composed of nano-particles or aggregates with a size of less than 10 nm. With the codoping of Ag + and La 3+, TiO 2 films with high photocatalytic activity and clearly responsive to the visible light were obtained. The improvement mechanism by ions doping was also discussed.