Microstructures and mechanical properties of heat-treated Al–5.0Cu–0.5Fe squeeze cast alloys with different Mn/Fe ratio

Abstract

The Al–5.0wt% Cu–0.5wt% Fe alloys with different Mn/Fe ratio were prepared by squeeze casting. Various test techniques, including tensile test, image analysis, scanning electron microscope (SEM), X-ray diffraction (XRD), electron probe micro-analyzer (EPMA) and transmission electron microscopy (TEM) were used to examine the microstructures and mechanical properties of the alloys in T5 heat-treated condition. The results show that the β-Fe (Al7Cu2Fe) is stable and its needle-like morphology is maintained after T5 heat treatment. However, the Chinese script AlmFe, α-Fe or Al6(FeMn) partially transform to a new Chinese script Cu-rich α(CuFe) (Al7Cu2Fe or Al7Cu2(FeMn)), which is harmful to the mechanical properties of the alloys due to the decrease of the Cu content in α(Al) matrix. The optimal Mn/Fe ratio is determined by the morphology of Fe-rich intermetallics, volume fraction of θ′ and T (Al20Cu2Mn3), size of α(Al) dendrite and porosity. Excessive Mn/Fe ratio will deteriorate the mechanical properties of the alloys due to the increase of the total amount of porosity and the Fe-rich intermetallics. When the Mn/Fe ratio is 1.6 and 1.2 for the applied pressure of 0MPa and 75MPa, respectively, the needle-like β-Fe phase is completely converted to the Chinese script Fe-rich intermetallics. The ultimate tensile strength, yield strength and elongation of the T5 heat-treated alloy with the Mn/Fe ratio of 1.2 and applied pressure of 75MPa reach 395MPa, 335MPa and 14%, respectively.