Microstructures and mechanical properties of as-cast Mg-Sm-Zn-Zr alloys with varying Gd contents

Abstract

The effect of Gd content on the microstructure and tensile properties of as-cast Mg-Sm-Zn-Zr alloy has been systematically investigated. In the Mg-3Sm-0.5Zn-0.5Zr alloy, the intermetallic compounds with multiple morphologies are identified as Mg3Sm phase. In addition to Mg3RE phase, Mg5RE phase originated from Gd addition is observed in Gd-modified alloys. It should be noted that the lattice parameters of all the observed intermetallic compounds are significantly reduced by Zn segregation. The segregation behavior of Zn in Mg3Sm phase is inhibited to some extent by Gd addition due to the electronegativity difference between Sm/Gd and Zn elements. In addition, the increased Gd content effectively leads to much more accumulation of solute atoms in front of the liquid-solid interface during solidification, which can prominently promote nucleation in liquid region and then refine grains. The tensile yield stress of the present alloys is thus improved with increasing Gd addition. Finally, Gd-modified alloys exhibit significantly age-hardening effect, which can be mainly attributed to the high-volume fraction and high density nano-scale precipitates.