Abstract
The outstanding combination of high strength and ductility of bridge cable steel wire is attributed to the cold drawing process with intermediate equivalent strain. However, the micro-structure-property relationship of heavily drawn steel wires for large span suspension bridge cables is not well understood. In this study, defects-controlled deformation in nano-scale interfaces between ferrite and cementite phases with heavily cold drawing process was investigated using high-resolution transmission electron microscopy and molecular dynamics simulation. The excessive thinning of the cementite lamellar thickness observed from the morphology suggested the evolution of the Fe3C/Fe interface in the cold-drawn wires, namely, the partial cementite deformation during the drawing process. Drawing strain played a major role in the occurrence of partial cementite nano-crystallisation. This was because the change in cementite morphology was the primary cause of cementite free energy increase, which ultimately led to cementite phase instability. The decrease of yield strength during the drawing process of the bridge cable steel wire was caused by the inverse Hall-Petch effect resulted from the nodule rotation. When the nodule morphology became flat, the inverse Hall-Petch effect was suppressed. At this time, the strengthening mechanism caused by cementite nano-crystallisation ensured the improvement of tensile strength of steel wire when the dislocation density was close to saturation.
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