Abstract
LaFe11.6Si1.4/16 wt%La70Co30 composites were fabricated by hot-pressing (HP) followed by thermal diffusion treatment in the temperature range of 923–1273 K. Significant microstructural and phase evolution occurred during diffusion heat treatment. Thermal decomposition (TD) occurred between 1023 and 1223 K, which increased the Curie temperature (TC) but smeared out the magnetic transition, decreasing magnetic entropy change (–ΔSM). Co atoms first diffused into the α-Fe(Si) and LaFeSi (1:1:1) phases. And then, the α-Fe(Co,Si) and La(Fe,Co)Si phases, attached to large LaFe11.6Si1.4 particles, transformed to a NaZn13-type La(Fe,Co,Si)13 (1:13) phase at 1273 K. Hence, a core-shell La(Fe,Co,Si)13 phase formed, resulting in a table-like magnetic entropy change over a wide temperature range (∼202–292 K). Greater Co diffusion and more homogeneity of the composition of the 1:13 phase could be achieved by increasing the annealing time. The maximum magnetic entropy change (–ΔSM)max of the composites at 0–2 T could be increased from 5.62 J/(kg·K) at ∼196 K to 8.81 J/(kg·K) at ∼244 K.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
