Microstructure performance and formation mechanism of laser alloying rare earth oxides modified nanocrystalline layer on TA7

Abstract

Nanoscale particles (NP) were observed in a Ni60–Ag–Si3N4–Y2O3 laser alloying (LA) layer on a TA7 titanium alloy, NP usually locate on the grain boundaries, which are able to block the motion of dislocation in a certain extent. Such layer mainly consisted of γ-Ni, TiN, γ-(Fe, Ni), TiAg and lots of amorphous phases. The wear resistance of such layer with laser scanning speed 3mm/s was better than that of a LA layer with 6mm/s, which was mainly ascribed to an uniform microstructure and less defect of layer. The high laser scanning speed made the existing time of laser molten pool be shorter than before, favoring the formation of a fine microstructure. However, the defects, such as pores were produced in LA layer (higher scanning speed), decreasing the wear resistance.