Abstract
Transmission electron microscopy is used to study the microstructure of fluorite-like solid solutions formed in pulsed-laser evaporation vacuum condensates. The dependence of the shape and size of the crystallites on the condensate temperature and the type of stabilizing oxide is shown. The effect of the admixture cation is explained using the phase diagrams for the relevant binary oxide systems. The significance of the phase size effect for the stabilization of the fluorite-like solid solutions formed in fine vacuum condensates is ascertained.
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