Abstract
The microstructure of the thixoformed ZA27 alloy naturally aged for 5 years has been observed and analyzed. The results indicate that most of the original β + η laminar eutectics have changed into the structures that small α particles uniformly distribute in η phase matrix. Both the β phase and α’ phase have also decomposed. It is suggested that a continuous or dot-line α phase first precipitates in the β phase close to the eutectic η phase layer. Then eutectoid η phase nucleates or directly grows up from the eutectic η phase, which promotes the nucleation of eutectoid α phase or the direct growth of the α phase from the existing α phase. Subsequently, the resulting α + η phases grow towards the β phase inside, forming the regular laminar α + η structures. The laminar structures always continuously grow across the center α’ phase, which leads the α’ phase also to transform into regular α + η laminar structures. The laminar structures may crack possibly due to internal stress. The eutectoid η phase lamellae have a tendency of changing from laminar shape to particle form, resulting in the formation of non-laminar structures.
Highlights
Zn-Al alloys containing small amount of copper have been observed to be cost- and energy-effective substitutes to a variety of ferrous and non-ferrous alloys owing to their higher strength, better wear and friction properties, lower casting temperature and more abundant resources[1,2]
The results show that the as-cast microstructure of the ZA27 alloy can be well explained through analyzing its solidification process[10,11,12,13]
The microstructures of the alloys prepared by these two forming technologies are very different
Summary
Zn-Al alloys containing small amount of copper have been observed to be cost- and energy-effective substitutes to a variety of ferrous and non-ferrous alloys owing to their higher strength, better wear and friction properties, lower casting temperature and more abundant resources[1,2]. ZA27 is of particular interest because it has high values of tensile strength up to 450MPa at ambient temperature[3]. It suffers from degradation of mechanical properties due to easy formation of porosity because of its wide solidification interval[4,5]. The authors’ previous investigation indicated that the tensile properties of thixoformed ZA27 alloy were significantly improved because of the obvious decrease of porosity, compared with those of the permanent mould cast alloy[9]. It is known that the microstructures of Zn-Al alloys are very complicated because their solidification process involves peritectic and eutectic reactions, and a series of solid phase transformations[10].
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