Microstructure investigation of NiAl–Cr(Mo) interface in a directionally solidified NiAl–Cr(Mo) eutectic alloyed with refractory metal

Abstract

Abstract The microstructure of a directionally solidified NiAl–Cr(Mo) eutectic alloyed with refractory metal in as-processed and heat-treated states has been studied by means of scanning electron microscopy and high resolution electron microscopy (HREM). The microstructure of the NiAl–Cr(Mo) eutectic was characterized by lamellar Cr(Mo) phases embedded within NiAl matrix with common growth direction of 〈1 1 1〉. The interface between NiAl and lamellar Cr(Mo) did not have any transition layers. Misfit dislocations were observed at the NiAl–Cr(Mo) interface. In addition to lamellar Cr(Mo) phases, coherent Cr(Mo, Ni, Al) precipitates and NiAl precipitates were also observed in the NiAl matrix and lamellar Cr(Mo) phases, respectively. After hot isostatic pressing and heat treatment, the NiAl–Cr(Mo) interfaces became smooth and straight. Square array of misfit dislocations was directly observed at the (0 0 1) interface between NiAl and Cr(Mo, Ni, Al) precipitate. The configuration of misfit dislocation network showed a generally good agreement with prediction based on the geometric O-lattice model.