Microstructure and mechanical properties of ZTA composites fabricated by oscillatory pressure sintering

Abstract

The influence of sintering temperature on the microstructure and mechanical properties of Al2O3−20wt% ZrO2 composites fabricated by oscillatory pressure sintering (OPS) was investigated by means of X-ray diffraction, scanning electron microscopy, three-point bending test and Vickers indentation. Results were compared to specimens obtained by conventional hot pressing (HP) under a similar sintering schedule. The optimum oscillatory pressure sintering temperature was found to be 1600°C; almost fully dense materials (99.94% of theoretical density) with homogeneous microstructure could be achieved. The highest flexural strength, fracture toughness and hardness of such composites reached 1145MPa, 5.74MPam1/2 and 19.08GPa when sintered at 1600°C, respectively. Furthermore, the oscillatory pressure sintering temperature could be decreased by more than 50°C as compared with the HP method, OPS favouring enhanced grain boundary sliding, plastic deformation and diffusion in the sintering process.