Microstructure and Mechanical Properties of Spark Plasma Sintered Nanocrystalline TiAl-xB Composites (0.0 <x<1.5 at.%) Containing Carbon Nanotubes

Abstract

This paper investigates the effects of minor additions of carbon nanotubes (CNTs) and boron on the structure and mechanical properties of nanocrystalline TiAl intermetallic compound. Nanocrystalline TiAl-xB(0.0 < x < 1.5 at.%) composites containing 1 wt.% CNT were synthesized by mechanical alloying and spark plasma sintering. Microstructure and mechanical properties of samples were evaluated using a scanning electron microscopy, energy-dispersive x-ray spectroscopy, elemental mapping, differential scanning calorimetry, Vickers hardness measurement, and shear–punch test. The findings of the current study show that milling up to 40 h results in the formation of Ti(Al) solid solution. Further milling up to 60 h is associated with a complete amorphization of the structure. Results also show that spark plasma sintering leads to the transformation of Ti(Al) solid solution into a mixture of Ti3Al, Ti2Al, and TiAl intermetallic compounds. Minor additions of boron and CNTs cause a significant grain refinement. The addition of the latter significantly improves the elongation as well. The implications of boron/CNT additions for the microstructure of TiAl and how it correlates with the mechanical properties are thoroughly discussed in this paper.