Abstract

A novel metal matrix composite based on the NbMoCrTiAl high entropy alloy (HEA) was designed by the in-situ formation method. The microstructure, phase evolution, and compression mechanical properties at room temperature of the composite are investigated in detail. The results confirmed that the composite was primarily composed of body-centered cubic solid solution with a small amount of titanium carbides and alumina. With the presence of approximately 7.0 vol. % Al2O3 and 32.2 vol. % TiC reinforced particles, the compressive fracture strength of the composite (1542 MPa) was increased by approximately 50% compared with that of the as-cast NbMoCrTiAl HEA. In consideration of the superior oxidation resistance, the P/M NbMoCrTiAl high entropy alloy composite could be considered as a promising high temperature structural material.

Highlights

  • By introducing refractory elements including group IV (Ti, Zr, and Hf), V (V, Nb, and Ta), and VI (Cr, Mo, and W) in high entropy alloy (HEA), the developed refractory HEAs (RHEAs) possess high melting temperature, outstanding strength and hardness, high thermal stability, and softening resistance at elevated temperatures, which opens up the possibilities of the alloy developments satisfying structural demands at high temperature

  • The BCC WMoTaNb and WMoTaNbV HEAs maintained yield strength of 405 and 477 MPa at 1600 ◦ C respectively, which were much higher than that of Inconel 718 and Haynes 230 [9]. Most of these RHEAs are generally characterized with high density and poor high temperature oxidation resistance

  • Found, which suggested that the secondary phase grains and the HEA grains possessed good bonding

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Summary

Introduction

The concept of high-entropy alloys (HEAs), consisting of four or more principle metallic elements in equiatomic or near-equiatomic ratios, has attracted considerable interest owing to its tendency to form solid solution with outstanding mechanical and functional properties [1,2,3,4,5,6].By introducing refractory elements including group IV (Ti, Zr, and Hf), V (V, Nb, and Ta), and VI (Cr, Mo, and W) in HEAs, the developed refractory HEAs (RHEAs) possess high melting temperature, outstanding strength and hardness, high thermal stability, and softening resistance at elevated temperatures, which opens up the possibilities of the alloy developments satisfying structural demands at high temperature.Since the first WMoTaNb RHEA was reported in 2010, many literatures have been focused on the preparation methods and mechanical properties of RHEAs [7,8]. The BCC WMoTaNb and WMoTaNbV HEAs maintained yield strength of 405 and 477 MPa at 1600 ◦ C respectively, which were much higher than that of Inconel 718 and Haynes 230 [9]. Most of these RHEAs are generally characterized with high density and poor high temperature oxidation resistance. Such drawbacks are the current bottleneck for utilizing RHEAs as structural materials. In order to improve the oxidation resistance properties of the RHEAs, it was reported that the Ti, Al, Cr, and Si elements are essential

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