Microstructure and mechanical properties of cold sintered porous alumina ceramics

Abstract

New innovative approach to fabricate porous alumina ceramics by cold sintering process (CSP) is presented using NaCl as pore forming agent. The effects of CSP and post-annealing temperature on the microstructure and mechanical strength were investigated. Al2O3–NaCl composite with bulk density of 2.92 g/cm3 was compacted firstly using CSP and then a porous structure was formed using post-annealing at 1200°C–1500°C for 30 min. Brazilian test method and Vickers hardness test were used to determine the indirect tensile strength and hardness of the porous alumina, respectively. Meanwhile, the phases and the microstructure were respectively examined using X-ray diffractometer and scanning electron microscope (SEM) complemented by the 3D image analysis with X-ray tomography (XRT). SEM structural and XRT image analysis of cold sintered composite showed a dense structure with NaCl precipitated between Al2O3 particles. The NaCl volatization from the composite was observed during the annealing and then complete porous Al2O3 structure was formed. The porosity decreased from 48 vol% to 28 vol% with the annealing temperature increased from 1200 °C to 1500 °C, while hardness and mechanical strength increased from 14.3 to 115.4 HV and 18.29–132.82 MPa respectively. The BET analysis also showed a complex pore structure of micropores, mesopores and macropores with broad pore size distribution.