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Abstract
Portland cement pastes are highly heterogeneous material and exhibits heterogeneous features over a wide range of length scales. Mechanical properties of microstructure can be determined using depth-sensing indentation. Coupled indentation/SEM technique can be used to location the indents and provides a way to determine the mechanical properties of a specific phase. Thus, the present paper aims to determine the hardness of different phases of cement pastes prepared with different mineral admixtures including sugarcane bagasse ash. The microstructure of cement pastes prepared with different mineral admixtures is analyzed by X ray diffraction, scanning electron microscopy and dynamic hardness tests on polished sections. The different backscatter coefficient allows to differentiate anhydrous phases from C-S-H, calcium hydroxide, silica fume and quartz. A grid of indentation is used to determine the hardness of the different phases and a complete phase segmentation of the different samples is achieved. The results show that the hardness of the different phases follow the sequence (from higher to lower hardness) quartz, anhydrous particles, calcium hydroxide, C-S-H and agglomerated silica fume. The presence of agglomerated silica fume is clearly observed in scanning electron microscopy images and the poor mechanical properties of these areas might compromise the cement pastes. The microstructure of cement pastes prepared with sugarcane bagasse ashes is similar to the observed in samples with crushed quartz.
Highlights
Cement pastes are highly heterogeneous materials due to the multiple constituent phases and multiple processing conditions
This observation disagrees with the average particle size determined by laser granulometry which is explained by agglomeration of silica fume during measurements
Cement pastes were prepared with addition of quartz, silica fume and sugarcane bagasse ashes
Summary
Cement pastes are highly heterogeneous materials due to the multiple constituent phases and multiple processing conditions. Microstructure and general properties of the composite depend on the source materials, mixture proportions, conditions of curing and rate of hydration. Understanding the microstructure of cement pastes is important to understand the effect of processing conditions. Images of Portland cement pastes by scanning electron microscopy (SEM) have showed that pore structure is influence by the type of binder, curing time and the water/binder ratio[1]. SEM shows that the microstructure is complex and contains different phases [2,3]. Backscattered electrons SEM images have been used to differentiate phases within hydrated cement pastes. It is possible to separate particles of calcium hydroxide, residual unhydrated cement grains, C-S-H and pores [4,5]
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