Microstructural, thermal characterization and CMAS corrosion resistance of novel quaternary (Y0,25Er0,25Tm0,25Yb0,25)2Si2O7 high entropy disilicate material

Abstract

A novel (Y0,25Er0,25Tm0,25Yb0,25)2Si2O7 high entropy disilicate quaternary composition was synthesized from commercial oxide powders using ball milling and sintering processes as a candidate material for environmental barrier coatings (EBC). As-synthesized high entropy disilicate powders were sintered at different durations (12, 18, and 24 h) at 1600 °C in a muffle furnace before characterization. The XRD and SEM analyses revealed the single-phase monoclinic structure (β-type) with homogeneous elemental distribution for the sintered samples. The (Y0,25Er0,25Tm0,25Yb0,25)2Si2O7 samples exhibited low thermal diffusivity coefficient, low thermal conductivity, a close coefficient of thermal expansion (CTE) to SiC and a high temperature stability. The (Y0,25Er0,25Tm0,25Yb0,25)2Si2O7 samples were subjected to CMAS corrosion tests at 1300 °C with different durations (2, 12, and 24 h) to evaluate CMAS corrosion resistance. Additionally, Yb2Si2O7 samples were prepared and subjected to molten CMAS in the same way for comparison. Based on the results, the CMAS corrosion resistance was improved with (Y0,25Er0,25Tm0,25Yb0,25)2Si2O7 composition.