Abstract

Duplex Stainless Steels (DSS) and Superduplex Stainless Steels (SDSS) have a strong appeal in the petrochemical industry. These steels have excellent properties, such as corrosion resistance and good toughness besides good weldability. Welding techniques take into account the loss of alloying elements during the process, so this loss is usually compensated by the addition of a filler metal rich in alloying elements. A possible problem would be during the welding of these materials in adverse conditions in service, where the operator could have difficulties in welding with the filler metal. Therefore, in this work, two DSS and one SDSS were welded, by autogenous Tungsten Inert Gas (TIG), i.e., without addition of a filler metal, by three different heat inputs. After welding, microstructural, mechanical, and electrochemical analysis was performed. The microstructures were characterized for each welding condition, with the aid of optical microscopy (OM). Vickers hardness, Charpy-V, and cyclic polarization tests were also performed. After the electrochemical tests, the samples were analyzed by scanning electron microscopy (SEM). The SDSS welded with high heat input kept the balance of the austenite and ferrite, and toughness above the limit value. The hardness values remain constant in the weld regions and SDSS is the most resistant to corrosion.

Highlights

  • Duplex Stainless Steels (DSS) and Superduplex Stainless Steels (SDSS) are widely used in many industrial sectors, and have a strong appeal in the petrochemical industry

  • Due to the obtaining of many micrographs, for the three steels analyzed for three different heat inputs, it was chosen in this work to show the microstructural characterization of the regions for the three steels in the lower heat input and greater heat input, Figures 2–7

  • In the heat affected zone (HAZ) and weld metal (WM), besides the ferrite, there is austenite in three morphologies:

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Summary

Introduction

Duplex Stainless Steels (DSS) and Superduplex Stainless Steels (SDSS) are widely used in many industrial sectors, and have a strong appeal in the petrochemical industry. Applied to oil extraction structures, pipes, and pressure vessels, these steels combine good mechanical properties with an excellent ability to withstand the corrosive media to which they are exposed. These characteristics are directly linked to the biphasic structure formed, composed basically of ferrite and austenite in approximately equal proportions [1,2,3,4,5,6,7,8,9,10,11,12,13,14]. The filler metals are manufactured to compensate possible losses of alloying elements during welding of base metal (BM), and their chemical

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