Abstract

T92 steel tubes have been widely applied in advanced supercritical boilers to replace Gr.91 tubes. Simulated samples with microstructures similar to those present in the heat-affected zone (HAZ) of a T92 steel weld were subjected to short-term creep tests in the study. T92 steel tubes were normalized at either 1213 K (L) or 1333 K (H) for 1 h, followed by tempering (T) at 1033 K for 2 h. After the normalizing and tempering treatments, the HT samples comprised finer precipitates but in greater numbers along the prior austenite grain boundaries (PAGBs) and martensite lath boundaries, as compared with those of the LT samples. The HAZ microstructures in the T92 steel welds were simulated by using an infrared heating system, which included over-tempering (OT, below AC1) and partial transformation (PT, slightly below AC3) zones. Martensite laths in the OT sample were more likely to be replaced by numerous cellular structures or subgrains together with spherodized carbides mainly located at the lath and austenite grain boundaries. Furthermore, coarser but fewer carbides were found along the refined lath and grain boundaries in the PT samples, in comparison with other samples in each group. Short-term creep tests showed that the PT samples were more likely to fracture than other samples in each group. Moreover, under the same testing conditions, the microstructures of T92 steel were more stable and resistant to degradation than those of T91 steel after welding or loading at elevated temperatures. Such events were responsible for higher creep resistance of the simulated T92 samples than that of the simulated T91 samples under the same creep-rupture conditions.

Highlights

  • IntroductionBoilers in steam power plants are often constructed using 9-12 Cr creep-resistant steels [1]

  • Boilers in steam power plants are often constructed using 9-12 Cr creep-resistant steels [1].The extensive usage of ultra-supercritical (USC) fossil-fired power plants pushes the development of advanced ferritic steels, because such plants require improved creep-rupture strength and steam-oxidation resistance at 923 K

  • Increasing the normalizing temperature from 1213 K to 1333 K caused an increase in the martensite packet sizes and the prior austenite grain sizes (PAGSs) of the T92 steel

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Summary

Introduction

Boilers in steam power plants are often constructed using 9-12 Cr creep-resistant steels [1]. The extensive usage of ultra-supercritical (USC) fossil-fired power plants pushes the development of advanced ferritic steels, because such plants require improved creep-rupture strength and steam-oxidation resistance at 923 K. T92 steel (9Cr-0.5Mo-1.8W-VNbBN), which has good weldability [2], is one of the potential alloys applied in USC boilers [3]. The creep life of 9Cr ferritic steels can be improved by adding boron (B) to the alloys, which is associated with stabilized M23 C6 carbides at the grain boundaries [4,5]. The addition of B can decrease the hardness difference between distinct regions in modified 9Cr-1Mo steel welds [6]. Soluble B is responsible for repressing type

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