Microstructural evolution and mechanical properties of as-cast and directionally-solidified Nb-15Si-22Ti-2Al-2Hf-2V-(2, 14) Cr alloys at room and high temperatures

Abstract

Arc-melting (AC) and directional solidification (DS) techniques were used to prepare Nb-15Si-22Ti-2Al-2Hf-2V-(2, 14) Cr alloys (hereafter referred as to 2Cr and 14Cr alloys, respectively), and the microstructural evolution and mechanical properties, including Vickers hardness, room temperature fracture toughness and high temperature strength, of the two AC and DS alloys were compared. The results showed that with heat-treatment at 1350 °C for 50 h, the AC-2Cr alloy composed of Nb solid solution (NbSS) and α-Nb5Si3 silicide, while Laves C15-Cr2Nb phase arose in the 14Cr alloy. With two-phase NbSS/α-Nb5Si3 microstructure, the AC-2Cr alloy showed excellent room-temperature fracture toughness (KQ: 14.2 MPa m1/2) and 0.2% yield strength at 1250 °C (σ0.2: 315 MPa) and 1350 °C (σ0.2: 294 MPa), better than the AC-14Cr alloy with tri-phase NbSS/α-Nb5Si3/C15-Cr2Nb microstructure (KQ: 9.4 MPa m1/2, σ0.2: 189 MPa at 1250 °C and 87 MPa at 1350 °C). The DS technique was found not to change the phase constituent of each alloy, but it made the microstructure slightly orient to the growth direction, resulting in a significant improvement in room-temperature fracture toughness (by ∼43%) and high-temperature yield strength σ0.2 (by ∼55%), as compared with the AC samples.