Abstract
We advance a theory of microscopic solvent perturbations of pure radiative lifetimes, τ r, of (aromatic) · (inert-gas) n heteroclusters, which originate from intermolecular interactions between molecular multicentre transition monopoles and atomic point transition dipoles. This theory accounts well for the experimental τ r data of the S 1 state of 9,10-dichloroanthracene·R (RAr, Kr, Xe) heteroclusters. τ r is expected to serve as a useful probe for the interrogation of structure and dynamics of isomerization in heteroclusters.
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