Microscopic origin of multiple exciton emission in low-dimensional lead halide perovskites.

Abstract

Low-dimensional halide perovskites exhibit intriguing excitonic properties and emerge as an important class of self-activated luminescent materials. However, the ability to manipulate and optimize their luminescent properties is limited by the lack of the microscopic understanding of the exciton relaxation and emission and the inconsistency in the theoretical results in the literature. In this work, based on first-principles calculations, we studied excitons in 1D lead halide perovskites, C4N2H14PbBr4 and C4N2H14PbCl4, which are both bright visible-light emitters. We find that, in both compounds, the polaron-pair exciton (EX-PP) is more stable than the onsite exciton (EX-OS) and only the EX-PP emission energy from the calculation is close to the main photoluminescence (PL) peak observed in the experiment. The EX-OS is found to emit UV light in both compounds. Therefore, the EX-PP is responsible for the experimentally observed visible light emission in both C4N2H14PbBr4 and C4N2H14PbCl4. Furthermore, the calculated small energy difference between the EX-PP and EX-OS in C4N2H14PbBr4 suggests that the metastable EX-OS can be thermally populated at room temperature (RT); the calculated EX-OS emission energy agrees well with the energy of a minor PL peak observed at RT but not at 77 K. The validity our approach in the exciton calculation is supported by the benchmark of the calculated exciton emission energies against the experimental results in 13 0D and 1D metal halides. The discrepancies between this work and a recent theoretical study in the literature are also discussed.