Microscale heat transfer and phase change mechanisms of carbon dioxide at near-critical conditions

Abstract

Recent studies highlight the potential benefits of two-phase carbon dioxide (CO2) systems operating near their thermodynamic critical point. Significant heat transfer coefficients and resistance to critical heat flux from improved vapor phase properties can enable heat transfer and reliability enhancements. However, the physical mechanisms of phase change that govern heat transfer behavior in the near-critical regime of reduced pressures (0.85<PR<1, where PR=P/Pcrit) are not well understood. In the present study, subcooled microscale (hydraulic diameter, Dh=500μm) flow boiling experiments are conducted to elucidate the heat transfer behavior near the critical point and the underlying mechanisms that influence it. Experimental data reveals a deviation from the trends predicted by the Cheng correlation (Cheng, L et al., 2008, “New prediction methods for CO2 evaporation inside tubes: Part II—An updated general flow boiling heat transfer model based on flow patterns.” Int. J. Heat Mass Transfer), in particular, displaying a decreasing peak heat transfer coefficient as pressure increases. Heat transfer in the near-critical regime can be further partitioned into two regions: near-critical boiling (0.85<PR<0.96) that exhibits heat transfer highly dependent on surface temperature, and supercritical-like behavior (0.96<PR<1) exhibiting a strong heat transfer dependence on mass flux. High-speed side-view flow visualization reveals the dominant nucleation mechanism (heterogeneous or homogeneous) governs the heat transfer behavior and is adequately predicted using flow inlet conditions. The present study provides a method for predicting nucleation behavior, which, in turn, facilitates the prediction of heat transfer near the critical point. The continuous alteration of heat transfer in the near-critical regime as a function of PR is underscored by this mechanistic insight, bridging the gap between typical flow boiling (PR<0.85) and supercritical heat transfer (PR>1).