Abstract
Microporous organic polymers (MOPs) can be defined as materials with pore sizes smaller on average than 2 nm which are comprised of light, non-metallic elements such as C, H, O, N, and B. We describe here the main classes of MOPs which are conveniently sub-divided into amorphous and crystalline groups. We present an overview of the synthesis of these materials, along with some general design criteria for producing MOPs with high surface areas and micropore volumes. The advantages and disadvantages of MOPs with respect to inorganic materials such as zeolites and hybrid materials such as metal organic frameworks are discussed throughout, particularly in terms of practical applications such as catalysis, separations, and gas storage. We also discuss future opportunities in this area as well as the potential to unearth "undiscovered" MOPs among the large number of rigid backbone polymers and networks reported in the literature.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
