Abstract

Changes in the microheterogeneous structure of a network block polymer based on diene and epoxy blocks have been studied using the small-angle X-ray scattering technique with a position sensitive detector. The formation of a three-dimensional chemical bond network is shown to result in microphase separation of chemically distinct blocks. The resulting microphase structure is stabilized by the three-dimensional network which prevents the establishment of a thermodynamic equilibrium in the system over a wide temperature range.

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