Micromechanical property evolution and damage mechanism of coal subjected to ScCO2 treatment

Abstract

Carbon dioxide (CO2) injection into deep coal seams holds considerable significance in both carbon mitigation and enhanced recovery of clean coalbed methane (CBM). The CO2-coal interaction leads to changes in the physicochemical properties, potentially impacting the stability of the target sequestration coal reservoir. This study applied the nanoindentation, scanning probe microscopy (SPM), X-ray diffraction (XRD), and electron probe X-ray Micro-Analyzer (EPMA) techniques to probe the micromechanical property change and damage mechanism of coal subjected to ScCO2 injection. The result shows that the load-displacement behavior of the tested coal changes with continuous ScCO2 treatment, and the mechanical strength significantly weakens after 4 days of ScCO2 treatment. The nanoindentation test indicates that the peak and creep displacements of tested coal increased by 168.79 % and 1046.32 % respectively with 4-day ScCO2 treatment, inferring that the coal deformation increases and changes from elastic to plastic after ScCO2 injection. As the ScCO2 treatment time increases, Young's modulus and hardness of coal exhibit an exponential decay trend and rapidly decrease by 77.77 %∼89.76 % and 68.37 %∼81.63 % respectively after the initial 3-day treatment, followed by a slow decrease with the ScCO2 duration prolonging. The XRD and EPMA results show that the carbonate minerals reacted preferentially with ScCO2, and silicate minerals experienced gradual dissolution, while the amorphous carbon fluctuated almost unchanged in the tested coal. Carbonate minerals in tested coal have decreased by 70.68 % within the first 1-day ScCO2 treatment, making the most significant contribution to the initial rapid weakening of coal mechanics. The mineral distribution is closely related to the mechanical anisotropy of coal, which is confirmed by the phenomenon that the coal anisotropy gradually weakens with the mineral reaction process. It is inferred that the mineral component and distribution of coal seams are important indicators for evaluating the intensity of physical and chemical reactions in ScCO2-injected reservoirs, which directly determines the mechanical damage behavior of sequestration reservoirs. This research provides basic support for site selection and safety assessment of carbon sequestration in deep coal seams.