Abstract

Four cherts sampled in the East Pilbara craton (Western Australia) at Marble Bar (Towers Formation), North Pole Dome (Dresser and Apex Basalt Formation), and Kittys Gap (Panorama Formation) were studied for micro- and nanomineralogy and geochemistry to determine their protoliths and to provide new insights on the physico-chemical and biological conditions of their depositional environments. The Marble Bar chert was formed at the interface with a basaltic rock. Hydrothermal fluids leached major and trace elements from the basalt and silicified the protolith of this chert. The elements Fe, Mn, Si, Ca, Mg, REE, Au, Pd, Cr, and Ni precipitated as a microbanded iron formation (BIF) under reducing and alkaline conditions. The chert is composed of magnetite, carbonates, and quartz and forms a stromatolite-like structure. Later oxidizing fluids replaced magnetite and carbonates with Fe-Mn oxyhydroxides. They show vermicular microtextures and filamentous nanotextures. Each filament is composed of euhedral nanoscopic hematite. These oxides contain several thousands of ppm of N and C, and measured C/N ratios are similar to those observed in organic matter preserved in marine sediments, thus suggesting an organic activity.

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