Microdiamonds in paragneisses from the allochthonous unit of the Swedish Caledonides - precious testimony of the UHP metamorphism

Abstract

The highest grade allochthonous unit in the Scandinavian Caledonides is represented by the Seve Nappe Complex (SNC) that belongs to the Middle Allochthon. This unit is interpreted to be derived from the outermost margin of Baltica that is dominated by metasediments and amphibolites. Eclogites, peridotites and migmatites occur only locally. Nonetheless, detailed field studies followed by comprehensive analytical investigations of high grade rocks within the SNC led to the discovery of the ultra-high pressure metamorphism (UHPM) within eclogites, garnet pyroxenites and paragneisses from central and northern Jamtland in Sweden (e.g. Janak et al. 2013; Klonowska et al. 2014, 2015; Majka et al. 2014). Diamond, in addition to coesite, is an index mineral for the UHPM and the first microdiamonds in the SNC of the Swedish Caledonides were recently discovered in paragneisses from the Snasahogarna Mt. (Majka et al. 2014). After this discovery, reinvestigation of gneiss samples from the Areskutan Mt., the classical area, where thrusting was defined for the first time in the Scandes (Tornebohm 1888) and where the UHPM has been lately indicated by the thermodynamic modelling (Klonowska et al. 2014), resulted in findings of microdiamond inclusions in garnets. Microdiamonds were identified by the Raman microspectroscopy in two gneiss samples and they range in size between 1 and 3µm. Partial transformation of diamond to the disordered graphite is a common feature observed in these inclusions. Microdiamonds are found as single grains as well as multiphase inclusions together with disordered graphite and carbonates. Aside from microdiamond inclusions, single grain of moissanite, a natural form of SiC, has been also identified. Moissanite inclusion is 3µm across and exhibits negative crystal shape. In-situ moissanite has been found only in few places so far, including rocks from the ultra-high pressure terranes, eclogite and serpentinite from the Dabie-Sulu orogenic belt in China (Qi et al. 2007, Xu et al. 2008), dunite from Luobusa ophiolite in Tibet (Liang et al. 2014) and felsic granulites from Bohemian Massif (Perraki and Faryad 2014). Findings of the microdiamond inclusions in the allochthonous rocks that represent continental crust indicate the UHP metamorphism and subduction to mantle depths (>100km), whereas the occurrence of moissanite points to the highly-reducing conditions during this deep subduction. Increased number of discoveries of the UHPM in the SNC shed a new light on the subduction-exhumation processes involved in a formation of the Caledonian mountain chain in Scandinavia. A new tectonic model for this orogenic belt has been recently proposed by Majka et al. (2014), where authors introduce a ‘vacuum cleaner mechanism’ being responsible for an exhumation of the deeply subducted rocks.