Abstract

Microbubbles have gained universal interest due to their wide applications in water treatment, cosmetics, and pharmaceutical industry and potential applications in gas–liquid reactions such as hydrogenation and oxidation. However, microbubble formation in organic solvents has been seldom investigated. A controllable and efficient platform is built to investigate microbubble formation in organic solvents using a hydrophilic ceramic membrane and a hydrophobic polytetrafluoroethylene (PTFE) membrane. The effect of membrane wettability on the size of microbubbles is studied with the change of the liquid property and membrane type. Experimental results show that the sizes of microbubbles are in ranges of 130–453 μm and 59–387 μm using the hydrophilic ceramic membrane and the hydrophobic PTFE membrane, respectively. Microbubbles generated in organic solvents using the hydrophilic ceramic membrane are much larger than those in water, and the size of microbubbles formed using the hydrophobic PTFE membrane shows an opposite trend. Furthermore, an equivalent pore is introduced to develop mathematical model to predict the microbubble size, which agrees well with the experimental data.

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