Abstract

Diamond-Like Carbon (DLC) and Chemical Vapor Deposition (CVD)-diamond films have been widely utilized not only as a hard protective coating for molds and dies but also as a functional substrate for bio-MEMS/NEMS. Micro-texturing into these hard coated molds and dies provides a productive tool to duplicate the original mother micro-patterns onto various work materials and to construct any tailored micro-textures for sensors and actuators. In the present paper, the high density oxygen plasma etching method is utilized to make micro-line and micro-groove patterns onto the DLC and diamond coatings. Our developing oxygen plasma etching system is introduced together with characterization on the plasma state during etching. In this quantitative plasma diagnosis, both the population of activated species and the electron and ion densities are identified through the emissive light spectroscopy and the Langmuir probe method. In addition, the on-line monitoring of the plasmas helps to describe the etching process. DLC coated WC (Co) specimen is first employed to describe the etching mechanism by the present method. Chemical Vapor Deposition (CVD) diamond coated WC (Co) is also employed to demonstrate the reliable capacity of the present high density oxygen plasma etching. This oxygen plasma etching performance is discussed by comparison of the etching rates.

Highlights

  • Diamond-Like Carbon (DLC) and Chemical Vapor Deposition (CVD)-diamond films have been widely utilized as a protective coating of mechanical, functional and fashionoriented parts besides tools and dies [1]

  • When using the hollow cathode, two strong peaks are seen in the spectrum: OI peaks are mainly observed at k = 776.34 nm and 843.78 nm, respectively. This reveals that much amount of oxygen atoms are available for etching by using the hollow cathode oxygen plasma

  • The hollow cathode oxygen plasma etching method is proposed as an effective means for etching of DLC- and CVD-diamond coatings

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Summary

Introduction

Diamond-Like Carbon (DLC) and Chemical Vapor Deposition (CVD)-diamond films have been widely utilized as a protective coating of mechanical, functional and fashionoriented parts besides tools and dies [1]. The boron-doped diamond or nano-crystalline diamond coatings are favored for application to electrically conductive substrates and bio-actuators [2, 3]. Micro-textures or micropatterns on the metallic or polymer products and tools, work to reduce the friction and wear of their surfaces under the presence of minimum quantity lubrication (MQL) [4, 5]. The micro-textured DLC- and diamond-coatings are expected to further reduce the friction and wear under MQL and to work as a mold-die to duplicate their micro-textures onto the metallic and polymer sheets even without lubricating oils [6,7,8].

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