Micro solid phase extraction of cadmium and lead on a new ion-imprinted hierarchical mesoporous polymer via dual-template method in river water and fish muscles: Optimization by experimental design

Abstract

In the present study, a new class of hierarchical silica based imprinted mesoporous polymers was fabricated by ion imprinting technology and it was applied to simultaneous selective extraction of cadmium and lead ions by micro solid phase extraction (μ-SPE). The biological nanocrystalline cellulose (BNCC) was prepared via acid catalyzed hydrolysis of cotton wool. The hierarchical silica (HS), as a substrate material, was synthesized via dual-template method, using BNCC and cetyltrimethylammonium bromide (CTAB) as hard and soft templates respectively. The structure and functional groups was characterized by Fourier infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), X-ray diffraction (XRD) and nitrogen adsorption-desorption. The results indicate that the as-prepared material has a hierarchical mesoporous structure with high specific surface area and high adsorption capacity for Cd(II) and Pb(II). The optimum experimental conditions in the proposed procedure were determined by response surface methodology (RSM) based on Box Behnken Design (BBD) and then it was successfully applied to determine Cd(II) and Pb(II) ions in the river water and fish samples.