Abstract

Abstract This review gives a brief outline of various micellar properties of triblock polymers such as critical micellization concentration, critical micellization temperature, and microviscosity. Detailed discussion of the effect of temperature on micellar properties of various triblock polymer mixtures is given. Applications of triblock polymers in solubilization as drug delivery agents, as nano drug, for the synthesis of gold nanoparticles, for cobalt determination, etc. are discussed.

Highlights

  • Premature deterioration of concrete structures mainly occurs due to the ingress of chloride ions and carbon dioxide [1]

  • Some authors argue that those compounds which are used to protect concrete reinforcement are not effective [10] when the concrete is kept immersed in NaCl solution, whereas others report that some compounds are effective in reducing corrosion rate of steel rebar in concrete contaminated with chlorides [22, 23]

  • It is understandable from the polarization data that at very low concentration (50 ppm), sodium nitrite acted as a corrosion antagonist, i.e., the corrosion rate of steel rebar treated with nitrite was greater than that of the rebar immersed in concrete pore solution (CPS) without nitrite

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Summary

Introduction

Premature deterioration of concrete structures mainly occurs due to the ingress of chloride ions and carbon dioxide [1]. Some authors argue that those compounds which are used to protect concrete reinforcement are not effective [10] when the concrete is kept immersed in NaCl solution, whereas others report that some compounds are effective in reducing corrosion rate of steel rebar in concrete contaminated with chlorides [22, 23]. The present investigation aims to explain the behaviour of these chemical species on steel rebar in contaminated concrete pore solution. Chemicals such as trisodium citrate (98%), sodium chloride (> 99.9%), ­NaNO2 ­(EMSURE®) and zinc acetate (> 99%) were purchased from Merck Millipore. To investigate the surface morphological changes on the steel rod dipped in simulated concrete pore solution [46, 47], microscopic studies were performed using Leica Stereo Microscope (S8ACO)

Results and discussion
NaNO2 50ppm
Conclusions
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