Abstract
The effect of terminal unsaturation on the CMC values of sodium 11-dodecenoate and sodium 12-tridecenoate have been probed using conductance and 23 Na NMR. The results suggest that addition of a terminal double bond has the same effect on the CMC of the corresponding saturated sodium carboxylate as the removal of 1.1 CH 2 units. Our results confirm that the previous study of the above effect, observed for sodium 10-undecenoate, is probably a general one.
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