Abstract
Heteronuclear magnesium-iron carbonyl anion complexes MgFe(CO)4- and Mg2Fe(CO)4- are produced in the gas phase and are detected by mass-selected infrared photodissociation spectroscopy in the carbonyl stretching frequency region. The geometric structures and the metal-metal bonding are discussed with the aid of quantum chemical calculations. Both complexes are characterized to have a doublet electronic ground state with C3v symmetry containing a Mg-Fe bond or a Mg-Mg-Fe bonding unit. Bonding analyses indicate that each complex involves an electron-sharing Mg(I)-Fe(-II) σ bond. The Mg2Fe(CO)4- complex involves a relatively weak covalent Mg(0)-Mg(I) σ bond.
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