MFCI experiments on the influence of NaCl-saturated water on phreatomagmatic explosions

Abstract

Molten–Fuel–Coolant Interaction (MFCI) experiments were performed using remelted foiditic rock samples from the West Eifel volcanic field (Germany). Two experimental series were carried out with one magmatic melt and two water compositions. Bi-distilled water was used in the first series (DW-1 to DW-5). In the second series (SW-1 to SW-5), the bi-distilled water was saturated (350 g L − 1 ) with sodium chloride (NaCl). For both experimental series the fragmentation history and the energy release were recorded and compared. The smallest particles (≤ 125 μm) were studied using scanning electron microscopy (SEM). Most MFCI experiments with bi-distilled water reached higher explosion intensities than the experiments with the saline water. This was accompanied by higher particle ejection velocities as well as the formation of more fine-grained and more interactive particles of angular shape. Additionally, the smallest artificial pyroclasts were examined by evolved gas analyses (EGA). The particles from the MFCI experiments with salt solutions are found to contain more sodium hydroxide (NaOH). These observations can be explained by thermodynamic arguments. In contrast to the MFCI experiments with pure water, an additional reaction occurs with saline water that results in evolution of hydrogen chloride (HCl) gas and leaves a residue of sodium hydroxide. The MFCI process with saline water consumes more enthalpy and Gibbs free energy, so that less energy is available for the explosion. With other sodium halides dissolved in the water (NaF, NaBr or NaI) the additional reaction can be predicted to have greater or lesser effects on phreatomagmatic explosions.