Abstract
The CH 3 P radical, which may be produced in the pyrolysis of (CH 3 ) 3 P, has not been observed experimentally. Starting from the potential energy surfaces for the CH 3 P→CH 2 PH rearrangement, we examine the properties of the lowest singlet ( 1 A') and triplet ( 3 A 2 ) states of CH 3 P. The geometry optimizations are performed at the CISD level of theory with the TZ2P+f basis set. For the closed-shell singlet state ot CH 2 =PH, the highest level and basis set is the CCSD level with the TZ2P basis
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