Abstract
In the title compound, CH3OC(O)NHP(O)(OCH3)2, the P atom has a slightly distorted tetrahedral configuration. The mixed imide moiety can be described as cisoid–transoid in which the two opposing dipoles (P=O and C=O) are oriented with a O=C⋯P=O torsion angle of 150.88(18)°. In the crystal, molecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers.
Highlights
In the title compound, CH3OC(O)NHP(O)(OCH3)2, the P atom has a slightly distorted tetrahedral configuration
Supplementary data and figures for this paper are available from the IUCr electronic archives
O4 distorting the tetrahedral environment of the phosphorus atom
Summary
Department of Inorganic Chemistry, Kiev National Taras Shevchenko University, Vladimirskaya St. 64/13, Kiev 01601, Ukraine Selected geometric parameters (Å, ). R factor = 0.048; wR factor = 0.133; data-to-parameter ratio = 14.0. In the title compound, CH3OC(O)NHP(O)(OCH3)2, the P atom has a slightly distorted tetrahedral configuration. The mixed imide moiety can be described as cisoid–transoid in which the two opposing dipoles (P O and C O) are oriented with a O C P O torsion angle of 150.88(18) . In the crystal, molecules are linked by pairs of N—H O hydrogen bonds, forming inversion dimers. Hydrogen-bond geometry (Å, ).
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
