Abstract

The title compound {systematic name: 9,10-didehydro-N-[1-(hydroxy­meth­yl)prop­yl]-d-lysergamide maleate}, C20H26N3O2 +·C4H3O4 −, contains a large rigid ergolene group. This group consists of an indole plane connected to a six-membered carbon ring adopting an envelope conformation and N-methyl­tetra­hydro­pyridine where the methyl group is in an equatorial position. In the crystal, inter­molecular N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds form an extensive three-dimensional hydrogen-bonding network, which holds the cations and anions together.

Highlights

  • Background functionShifted ChebyschevPreferred orientation correction: March–Dollase (Dollase, 1986); direction of preferred orientation - 011, MD = 1.26Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) N1 C2 C3 C4 C5 C6 C7 C8

  • Supplementary data and figures for this paper are available from the IUCr electronic archives

  • This model was transferred to the z-matrix

Read more

Summary

Specimen mounted in transmission mode

H O, O—H N and O—H O hydrogen bonds form an extensive three-dimensional hydrogen-bonding network, which holds the cations and anions together

Related literature
This study was supported by the grant of the Czech Grant
Synchrotron radiation
Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call