Abstract
The title compound {systematic name: 9,10-didehydro-N-[1-(hydroxymethyl)propyl]-d-lysergamide maleate}, C20H26N3O2 +·C4H3O4 −, contains a large rigid ergolene group. This group consists of an indole plane connected to a six-membered carbon ring adopting an envelope conformation and N-methyltetrahydropyridine where the methyl group is in an equatorial position. In the crystal, intermolecular N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds form an extensive three-dimensional hydrogen-bonding network, which holds the cations and anions together.
Highlights
Background functionShifted ChebyschevPreferred orientation correction: March–Dollase (Dollase, 1986); direction of preferred orientation - 011, MD = 1.26Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) N1 C2 C3 C4 C5 C6 C7 C8
Supplementary data and figures for this paper are available from the IUCr electronic archives
This model was transferred to the z-matrix
Summary
H O, O—H N and O—H O hydrogen bonds form an extensive three-dimensional hydrogen-bonding network, which holds the cations and anions together
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