Abstract
The interaction and supramolecular assemblies of two alkaline earth metal ions, Ca2+ and Ba2+, with methyl-substituted cucurbit[6]uril derived from 3α-methyl-glycoluril (HMeQ[6]) in aqueous HCl solution have been investigated. X-ray diffraction analysis revealed that coordination of HMeQ[6] with these metal ions resulted in the formation of one-dimensional coordination polymers in the presence of polychloride transition metal anions, such as [CdCl4]2−, as structure-directing agents. The supramolecular frameworks exhibit excellent thermal stability as well as permanent porosity. The activated desolvated materials show high Et2O and CH3OH adsorption capacity and selectivity compared with other porous organic materials assembled solely through hydrogen bonding under ambient conditions.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
