Abstract
The title compound, C15H13NO2, was synthesized by N-alkylation of methyl bromoacetate with 9H-carbazole. The carbazole ring system is essentially planar (mean atomic deviation = 0.0346 Å) and makes a dihedral angle of 86.5 (7)° with the methyl acetate group. Weak intermolecular C—H⋯O hydrogen bonding is present in the crystal structure.
Highlights
The title compound, C15H13NO2, was synthesized by Nalkylation of methyl bromoacetate with 9H-carbazole
Weak intermolecular C— HÁ Á ÁO hydrogen bonding is present in the crystal structure
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: XU2513)
Summary
Key indicators: single-crystal X-ray study; T = 93 K; mean (C–C) = 0.003 A; R factor = 0.055; wR factor = 0.143; data-to-parameter ratio = 15.9. The title compound, C15H13NO2, was synthesized by Nalkylation of methyl bromoacetate with 9H-carbazole. The carbazole ring system is essentially planar (mean atomic deviation = 0.0346 A ) and makes a dihedral angle of 86.5 (7) with the methyl acetate group. Weak intermolecular C— HÁ Á ÁO hydrogen bonding is present in the crystal structure. Related literature The title compound is an intermediate in the synthesis of -(9carbazole) acetyl chloride, a novel fluorescence derivatization reagent, see: Xie et al (2006); Bong et al (1992). See: Allen et al (1987). See: Xie et al (2006)
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