Abstract

In the title compound, C22H21N3O4, the central pyrrolidine ring adopts an envelope conformation with the N atom in the flap position. The indoline ring systems are almost perpendic­ular to the mean plane of the pyrrolidine ring, making dihedral angles of 86.4 (8) and 83.1 (8)°. The acetate group attached to the pyrrolidine ring assumes an extended conformation. In thecrystal, N—H⋯O hydrogen bonds result in the formation of a C(7) chain running along [100]. The crystal packing also features π–π inter­actions [centroid–centroid distance = 3.2032 (11) Å].

Highlights

  • Crystal dataMethyl (3R*,30 S*)-10 ,10 0 -dimethyl-2,20 0 dioxodispiro[indoline-3,20 -pyrrolidine30 ,30 0 -indoline]-40 -carboxylate

  • In the title compound, C22H21N3O4, the central pyrrolidine ring adopts an envelope conformation with the N atom in the flap position

  • The indoline ring systems are almost perpendicular to the mean plane of the pyrrolidine ring, making dihedral angles of 86.4 (8) and 83.1 (8)

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Summary

Crystal data

Methyl (3R*,30 S*)-10 ,10 0 -dimethyl-2,20 0 dioxodispiro[indoline-3,20 -pyrrolidine30 ,30 0 -indoline]-40 -carboxylate. 103, India, bIndustrial Chemistry Laboratory, Central Leather Research Institute, Adyar, Chennai 600 020, India, and cDepartment of Physics, Presidency College (Autonomous), Chennai 600 005, India. R factor = 0.043; wR factor = 0.110; data-to-parameter ratio = 13.9

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