Abstract
The title compound, C24H27FN2O4, is an important intermediate in the synthesis of fungicidal strobilurin-type compounds. In the crystal structure, the oxime bond attached to the cyclopropane ring adopts a Z configuration, while the oxime bond attached to the benzene ring adopts an E configuration. The fluoromethylphenyl group adopts a trans configuration with respect to the remainder of the molecule, and its mean plane forms a dihedral angle of 56.1 (1)° with the plane of the cyclopropane ring.
Highlights
Structure Reports OnlineKey indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.003 A; R factor = 0.046; wR factor = 0.140; data-to-parameter ratio = 14.1
The title compound, C24H27FN2O4, is an important intermediate in the synthesis of fungicidal strobilurin-type compounds
The oxime bond attached to the cyclopropane ring adopts a Z configuration, while the oxime bond attached to the benzene ring adopts an E configuration
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.003 A; R factor = 0.046; wR factor = 0.140; data-to-parameter ratio = 14.1. The title compound, C24H27FN2O4, is an important intermediate in the synthesis of fungicidal strobilurin-type compounds. The oxime bond attached to the cyclopropane ring adopts a Z configuration, while the oxime bond attached to the benzene ring adopts an E configuration. The fluoromethylphenyl group adopts a trans configuration with respect to the remainder of the molecule, and its mean plane forms a dihedral angle of 56.1 (1) with the plane of the cyclopropane ring. Related literature For synthesis details and related literature, see: Li et al (2008); Ross et al (2001)
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