Abstract
We evaluate the applicability of an optical transmission measurement method commonly used for the analysis of the Black Carbon (BC) content of aerosol sample, to determine the BC content of loess sediments. A number of different sample pretreatment procedures are developed and com- pared, leading to an optimum preparation process. The results include: 1) Subtraction of the opti- cal attenuation values before and after heating of the sample filters (ΔATN) varies linearly with the sample mass. The slope of the regression line provides the best determination of BC concen- tration. 2) When the sample mass is small, (NaPO3)6 pretreatment is best for BC measurement, and the BC concentration results are given by the slope of the regression between ΔATN and sample mass, for a series of samples of varying mass. 3) HF pretreatment accompanied by centrifugation and rinsing may produce a negative bias on the result. 4) Replicate measurements of BC for loess samples showed a maximum deviation less than 5.6%, suggesting that measurements of the BC concentration of a sequence of loess samples could determine variations to this degree of signi- ficance. 5) The overall trends of BC concentration in loess section sequences were similar for all chemical pretreatments. The BC concentration result for replicate samples is comparable when pretreated by the same procedure.
Highlights
BC particles are ubiquitously present in our environment: both suspended as aerosols in the atmosphere, and in liquid and solid media after deposition to soils, loess, and aquatic sediments [1]-[4]
2) When the sample mass is small, (NaPO3)6 pretreatment is best for BC measurement, and the BC concentration results are given by the slope of the regression between ΔATN and sample mass, for a series of samples of varying mass
Our progress was the improvement of optical method for BC measurement of dust aerosol samples, because Hansen et al didn’t considered that the minerals of dust might be changed due to heating [39]
Summary
BC particles are ubiquitously present in our environment: both suspended as aerosols in the atmosphere, and in liquid and solid media after deposition to soils, loess, and aquatic sediments (both lacustrine and marine) [1]-[4]. The continuum of properties from char and charcoal to soot particles does not have clear-cut boundaries [9], but the entire class of material is recognized to have large impacts on the global atmospheric carbon cycle and provides a record of fire history [2] [7] [10]-[12]. Due to its inertness and thermal stability [5], BC transfers carbon from the rapid atmosphere-biosphere cycle into a much slower geological cycle. It may represent a significant sink in the global carbon cycle [13]-[16]. BC values measured by different groups using different methods gave markedly different results [20] [21]
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