Abstract
The work studies the issues associated with the construction of the equation of state (EOS) taking due account of substance behavior in the critical region and associated with the scaling theory of critical phenomena (ST). The authors have developed a new version of the scaling hypothesis; this approach uses the following: a) substance equation of state having a form of a Schofield-Litster-Ho linear model (LM) and b) the Benedek hypothesis. The Benedek hypothesis has found a similar behavior character for a number of properties (isochoric and isobaric heat capacities, isothermal compressibility coefficient) at critical and near-critical isochors in the vicinity of the critical point. A method is proposed to build the fundamental equation of state (FEOS) which satisfies the ST power laws. The FEOS building method is verified by building the equation of state for argon within the state parameters range: up to 1000 MPa in terms of pressure, and from 83.056 К to 13000 К in terms of temperature. The executed comparison with the fundamental equations of state of Stewart-Jacobsen (1989), of Kozlov at al (1996), of Tegeler-Span-Wagner (1999), of has shown that the FEOS describes the known experimental data with an essentially lower error.
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