Methanol assisted selective formation of 1,2-glycerol carbonate from glycerol and carbon dioxide using nBu 2SnO as a catalyst

Abstract

Selectively 1,2-glycerol carbonate was obtained from glycerol and carbon dioxide in methanol using 1 mol% n Bu 2SnO (dibutyltin(IV)oxide, 1) as a catalyst. The reaction attained equilibrium in 4 h and the yield of 1,2-glycerol carbonate obtained was as high as 35%. We observed the rate of the reaction depends on the amount of the catalyst and methanol used. During the reaction we could trap the intermediates and identify it by 13C NMR, IR and mass spectrum of the reaction mixture. The reaction proceeds upon activation of 1 by methanol forming dibutyltindimethoxide followed by dibutyltinglycerate, which undergoes CO 2 insertion to produce non-isolable 7-membered tin–glycerolcarbonato complex that finally yield glycerol carbonate. Catalyst 1 was found to be successful even with 1,2-propanediol and ethylene glycol yielding the corresponding cyclic carbonate.