Methane abatement under stoichiometric conditions on perovskite-supported palladium catalysts prepared by flame spray synthesis

Abstract

Three-way catalysts (TWC) are the key technology to reduce emissions of pollutants from stoichiometric engines. Perovskite-type catalysts of general formula ABO3±δ (A=La, Y; B=Mn, Fe) containing 2wt% Pd were produced by flame spray synthesis (FSS) using metal nitrate precursors. The structural properties of the catalysts were characterized by X-ray diffraction (XRD), surface area determination (BET) and transmission electron microscopy (TEM). Crystalline metal oxide nano-particles of 20nm average size were accompanied by minority La2O3 and Y2O3 phases. The state of Pd in the catalysts was characterized using X-ray photoelectron spectroscopy (XPS), X-ray absorption near edge spectroscopy (XANES) and CO adsorption by infrared spectroscopy. Metallic Pd coexisted with Pd in oxidation state +2 and higher on all fresh samples. TEM confirmed the presence of dispersed Pd particles 2–5nm in diameter. Therefore, under the chosen synthesis conditions, FSS provides supported palladium nano-particles rather than a solid solution. PdO was the dominant Pd species after calcination at 700°C. The TWC activity was tested in a simulated stoichiometric gas mixture comprising CH4, CO, NOx and O2. PdO in combination with YFeO3±δ exhibited the lowest temperature for CH4 oxidation (T50=450°C), which was ca. 100°C lower than that of the sample obtained by the conventional wet-chemical method. After cycling under reaction conditions up to 850°C, a large improvement of catalytic activity for CH4 oxidation was observed which associated with the formation of metallic Pd particles (ca. 20nm) and the hexagonal→orthorhombic phase transition of YFeO3±δ.