Abstract
Trains and boats and planes: The thermolysis of a triruthenium complex having μ3-pentylidyne and μ3-pentyne ligands on each face of the trimetallic plane exclusively afforded the μ3-ethylidyne-μ3-octyne complex. In this reaction, a C3 fragment migrated from one face of the Ru3 plane to the other. This corresponds to the selective redistribution of two C5 molecules into C2 and C8 molecules.
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