Metastable ion study of substituted cyclopentadienylmanganese cations in the gas phase

Abstract

The behavior of some substituted cyclopentadienylmanganese ions has been studied by tandem mass spectrometry. This metastable ion study showed that only C 5H 5Mn + and (C 5H 4CN)Mn + ions retain their nido-cluster structure ( 1), which is characterized by a simple metal-ligand bond cleavage. Other substituted ions, RXC 5H 4Mn +, rearrange to a different extent, depending on the nature of the substituent. The first rearrangement step is R radical migration to the central metal atom, leading to RMnC 5H 4X +-type ions ( 2). These ions decompose by elimination of X (for X = CO) or with formation of RMn +, but further rearrangements can also occur. These are the reverse migration of R from the metal atom to the π-ligand (for R = H, Ph) and cyclopentadienyl ring expansion (for X = Ch 2). Collisional activation mass spectra contained an Mn + ion peak, which can indicate the existence of stable type 1 structures for most cyclopentadienylmanganese ions. Carboxyl and hydroxymethyl derivatives exist, presumably as ions of type 2. The neutralization-reionization mass spectra of RXC 5H 4Mn + ions are also discussed.