Abstract
An electropolymerized polyacrylonitrile layer (200 nm thick) was studied by metastable de-excitation spectroscopy (He 2 3S) and UV photoelectron spectroscopy (HeI). We show that this layer has both insulating and conducting properties. Its electronic properties and its dielectric behaviour change appreciably after reticulation and with temperature. The importance of the nitrile group in the understanding of these properties is emphasized.
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