Abstract

Multi-electron−ion coincidence spectroscopy is applied for investigating metastability of the dication states formed by the S 2p Auger decay in OCS. The coincidence spectrometer developed in the present work is based on a magnetic-bottle time-of-flight electron spectrometer equipped with electrostatic retardation and ion detection capabilities. Dication spectroscopy with a fairly-high energy resolution and high statistics enables us to inspect the metastability of the individual electronic states in OCS2+.

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