Abstract
The energy storage sector facilitates research on the development of novel electrodes for metal-ion batteries, and economic catalysts for metal-air batteries, fuel cells and water-splitting devices. In Li-ion batteries (LIB), after the great success of LiFePO4 as a cathode, phosphate-based materials have been extensively studied. LIB empower suites of portable electronics and (hybrid) electric vehicles, while for large-scale micro-to-mega stationary grid storage purposes a more economical option such as sodium-ion batteries (SIB) has been developed. In this quest, the viability of metaphosphate as a cathode for SIB has been recently explored where NaTM(PO3)3 [TM = Fe, Co] showed reversible Na+ (de)intercalation.
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