Metamorphosed Plio-Pleistocene evaporites and the origins of hypersaline brines in the Salton Sea geothermal system, California: Fluid inclusion evidence

Abstract

The Salton Sea geothermal system (SSGS) occurs in Plio-Pleistocene deltaic-lacustrine-evaporite sediments deposited in the Salton Trough, an active continental rift zone. Temperatures up to 365°C and hypersaline brines with up to 26 wt.% TDS are encountered at 1–3 km depth in the sediments, which are undergoing active greenschist facies hydrothermal metamorphism. Previous models for the origins of the Na-Ca-K-Cl brines have assumed that the high salinities were derived mainly from the downward percolation of cold, dense brines formed by low-temperature dissolution of shallow non-marine evaporites. New drillcores from the central part of the geothermal field contain metamorphosed, bedded evaporites at 1 km depth consisting largely of hornfelsic anhydrite interbedded with anhydrite-cemented solution-collapse shale breccias. Fluid inclusions trapped within the bedded and breccia-cementing anhydrite homogenize at 300°C (identical to the measured downhole temperature) and contain saline Na-Ca-K-Cl brines. Some of the inclusions contain up to 50 vol.% halite, sylvite and carbonate crystals at room temperature, and some halite crystals persist to above 300°C upon laboratory heating. The data are consistent with the trapping of halite-saturated Na-Ca-K-Cl fluids during hydrothermal metamorphism of the evaporites and accompanying solution collapse of interbedded shales. We conclude that many of the salt crystals in inclusions are the residuum of bedded evaporitic salt that was dissolved during metamorphism by heated connate fluids. Therefore, the high salinities of the Salton Sea geothermal brines are derived in part from the in situ hydrothermal metamorphism and dissolution of halides and CaSO 4 from relatively deeply-buried lacustrine evaporites. This fact places important constraints on modeling fluid-flow in the SSGS, as brines need not have migrated over great distances. The brines have been further modified to their present complex Na-Ca-K-Fe-Mn-Cl compositions by on-going sediment metamorphism and water-rock interaction.